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+-SH safe2241515 +-SH artist:poecillia-gracilis19143 +-SH princess cadance41515 +-SH princess celestia115852 +-SH princess luna120371 +-SH shining armor29002 +-SH alicorn330175 +-SH pony1672164 +-SH g42103177 +-SH absurd resolution68889 +-SH clothes665172 +-SH crown31964 +-SH grin66082 +-SH gritted teeth20368 +-SH jewelry121755 +-SH looking at something5501 +-SH open mouth252291 +-SH ponified53095 +-SH queen elizabeth ii34 +-SH regalia39239 +-SH royal sisters7294 +-SH shocked10531 +-SH smiling423134 +-SH varying degrees of want1122
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“Passionate about whatever she’s watching” would be more accurate methinks, as it includes “angry” without the grin (viewer’s first impression) and “heck yeah!” with it (after a second look).
But she looks like she’s furrowing her brow, hence “angry.”
I admit that it’s not obvious at first sight. You have to take a close look at the corner of her mouth to see that it’s actually curling up.
Edited
Without the original pic to reference, I wouldn’t see it that way. The artist accidentally made Celestia look like she’s gritting her teeth (or sucking air through them in order to hold her tongue).
She’s not, that’s actually a toothy grin.