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Well quack medicines or patent medicines often had all sorts of drugs alongside alcohol. including heroin, morphine, cocaine, cannabis(many legitimate medicines also had this before it was made illegal), even Acetanilide which is very toxic but functioned similar to aspirin before that came along.
(Obscure? Just go see Ken Griffey’s grotesquely swollen jaw!)
Green liquid coke!
Though has anyone actually looked through some of those to make positively sure there did happen to actually be something to one of those old things?