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+-SH safe2204048 +-SH artist:poecillia-gracilis19143 +-SH princess cadance40640 +-SH princess celestia114053 +-SH princess luna118503 +-SH shining armor28475 +-SH alicorn320889 +-SH pony1634560 +-SH g42059658 +-SH absurd resolution68023 +-SH clothes647491 +-SH crown30791 +-SH grin64248 +-SH gritted teeth19819 +-SH jewelry116933 +-SH looking at something5208 +-SH open mouth244048 +-SH ponified51542 +-SH queen elizabeth ii34 +-SH regalia37650 +-SH royal sisters6984 +-SH shocked10299 +-SH smiling408243 +-SH varying degrees of want1098
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“Passionate about whatever she’s watching” would be more accurate methinks, as it includes “angry” without the grin (viewer’s first impression) and “heck yeah!” with it (after a second look).
But she looks like she’s furrowing her brow, hence “angry.”
I admit that it’s not obvious at first sight. You have to take a close look at the corner of her mouth to see that it’s actually curling up.
Edited
Without the original pic to reference, I wouldn’t see it that way. The artist accidentally made Celestia look like she’s gritting her teeth (or sucking air through them in order to hold her tongue).
She’s not, that’s actually a toothy grin.