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Mad Black
Cool Crow - "Caw!" An awesome tagger
Magnificent Metadata Maniac - #1 Assistant
Speaking Fancy - For helping with translations
The End wasn't The End - Found a new home after the great exodus of 2012

@Chaotic Note
Sunny Flare, Indigo Zap, Twilight Sparkle? That’s half that aren’t sweet related.
 
Well Sunny Flare and Indigo Zap sound like soft drinks, just like Capri Sun.  
full
 
Also isn’t Indigo also a plant? Baptisia aka. Wild Indigo and Indigofera?  
There is even a flower called Rosa Sun Flare and Lemon Zest petunias.  
Also in some recepts for sweet you suger coat, or candied some flowers and put them on your pastries.  
Sour Sweet has Synsepalum dulcificum in her hair. Those berries are used to make sour thing like lemons and limes taste sweet.
 
So the names are probably more clever than we thought.
Background is Best Pony
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irrelevant pone
Since everybody is guessing, I’ll throw in my 2 cents
 
Sunset vs Twilight  
Pinkie vs Sunny  
Rarity vs Lemon  
Rainbow vs Indigo  
Fluttershy vs Sour Sweet  
Applejack vs Sugarcoat
NicoleLady

My guess:  
AJ vs Twi  
Flutters vs sour sweet  
Dash vs zap  
Sunset vs sugar coat  
Rarity vs sunny flare  
And  
Pinkie vs lemon zest
Background Pony #4524
so we had altenate lighting dust, trixies twin, sonata wannabe, dark derpy, and aria Little sister
Background Pony #9317
If you look at the toyline there are 3 competitions and this is how the teams break down.
 
Archery: Twilight, Sour Sweet, Applejack, Fluttershy.  
Roller Derby: Pinkie, Rarity, Sunny Flare, Lemon Zest.  
Motorcross: Sunset Shimmer, Rainbow Dash, Sugarcoat, Indigo Zap.
Mad Black
Cool Crow - "Caw!" An awesome tagger
Magnificent Metadata Maniac - #1 Assistant
Speaking Fancy - For helping with translations
The End wasn't The End - Found a new home after the great exodus of 2012

 
If you look in the background you can see that fluttershy has here the same hairstyle like Sour Sweet in the picture above.  
Also I think they took parts of the colorpallets from the original Designs. Like Posey (different yellow and pink), Maple jack (red and green coloration of AJ), and Raritys body was this blue before they decided to go with white.
Mad Black
Cool Crow - "Caw!" An awesome tagger
Magnificent Metadata Maniac - #1 Assistant
Speaking Fancy - For helping with translations
The End wasn't The End - Found a new home after the great exodus of 2012

Name wise and color wise I would say  
Lemon Zest = AppleJack  
Sugar Coat = Pinkie Pie  
Indigo Zap = Rainbow Dash  
Sunny Flare = Rarity  
Sour Sweet = Fluttershy.
 
In the trailer you can even see Sour Sweet and Fluttershy in the same competition.  
I guess they will be defined by their differences and not the similarities. That they are in some regard equal opposites.
Zeyon

So they are rivals, and going to compete against individual members of the human mane 6? I’m guessing:  
Sour sweet = AJ (Freckles)  
Lemon Zest = Pinkie Pie  
Indigo Zap = Dash  
Sugar Coat = Rarity  
Sunny Flare = Fluttershy