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SuperSonic15
An Artist Who Rocks - 100+ images under their artist tag
Artist -

@DoomPony  
Who can blame her?
 
She invited Discord to liven things up, despite being soaked in Smooze slime and being unable to use her Alicorn magic to restore order for a short while, and she ends up being in an even happier mood at the end of the episode, despite her worry and anger when she is unable to stop the Smooze and trying to protect the other guests from it until Discord intervened.
SuperSonic15
An Artist Who Rocks - 100+ images under their artist tag
Artist -

@pwingbrony  
Agreed.
 
She did giggle at one of his wisecracks while trying to get Fluttershy to feel guilty over not taking him to the Gala instead of Tree Hugger. And she did not mind the chaos caused by the Smooze afterwards, even though it did discomfort her with blocking her from using her magic by covering the tip of her horn with slime, then having to protect the other guests, after being cleaned off thanks to Tree Hugger calming Smooze down, as the Smooze advanced on her with the rest of the Mane Six trapped inside of him before Discord intervened and returned the Smooze to normal.
 
@mercurypony  
Second one she’s worn in the series if you count her coronation dress and crown from Magical Mystery Cure.
SuperSonic15
An Artist Who Rocks - 100+ images under their artist tag
Artist -

This is the second time we see Celestia wearing something other than her tiara, horseshoes, and collar since her crown and coronation attire back in Magical Mystery Cure.
 
Glad to see the writers being a little more varied with her now, even if it was her first appearance in Season 5.
 
I almost thought that she would be attending the Gala like back in The Best Night Ever in her regular appearance. Not to mention how giddy she sounded at the end with how, despite what happened with being soaked in slime by the Smooze and the chaos it caused, she still was having a wonderful time. That’s the Solar Sovereign for you now that she and Discord are on much friendlier terms now.
wantfastcars

“You know, I guess, just to fuck with ponies, just this ONCE… I’ll actually wear clothes to the most formal event of the year. Just this once.”
JP
Nightmare in the Moon - Had their OC in the 2024 Derpibooru Collab.
Pixel Perfection - I still call her Lightning Bolt
Silly Pony - Celebrated the 13th anniversary of MLP:FIM, and 40 years of MLP!
Shimmering Smile - Celebrated the 10th anniversary of Equestria Girls!
Solar Guardian - Refused to surrender in the face of the Lunar rebellion and showed utmost loyalty to the Solar Empire (April Fools 2023).
Roseluck - Had their OC in the 2023 Derpibooru Collab.
King Sombra - Celebrated the 10th anniversary of The Crystal Empire!
A Lovely Nightmare Night - Celebrated the 12th anniversary of MLP:FIM!
Princess of Love - Extra special version for those who participated in the Canterlot Wedding 10th anniversary event by contributing art.
Elements of Harmony - Had an OC in the 2022 Community Collab

I miss the show so much
Nice dress. Simple, but not too simple.
 
But you really should invest in shoes. You’re always wearing the same shoes in all occasions.